Dortmund Data Bank

Vapor-Liquid Equilibrium Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 422

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 CH4O 32.042 67-56-1 Methanol
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Constant Value

Temperature 308.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]
30.704 0.05000 0.14300
33.771 0.10000 0.26300
36.637 0.15000 0.35700
39.410 0.20000 0.43100
41.757 0.25000 0.49000
43.850 0.30000 0.53900
45.383 0.35000 0.58000
46.743 0.40000 0.61000
47.676 0.45000 0.63500
48.329 0.50000 0.65400
48.649 0.55000 0.66800
48.889 0.60000 0.68400
49.049 0.65000 0.69200
49.183 0.70000 0.70400
49.103 0.75000 0.71400
48.863 0.80000 0.72400
48.529 0.85000 0.74400
47.356 0.90000 0.77600
45.330 0.95000 0.84500

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Kireev V.A.; Sitnikov I.P.: Bestimmung des Druckes und der Zusammensetzung des Dampfes und der Verdampfungswärme von Methanol-Chloroform-Mischungen und freie Energie und Entropie bei der ihre Bildungen. Zh.Fiz.Khim. 15 (1941) 492-499


Vapor-Liquid Equilibrium Data Set 423

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Constant Value

Temperature 322.45 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]
58.875 0.05000 0.13800
64.355 0.10000 0.25400
69.968 0.15000 0.35000
74.607 0.20000 0.42400
78.140 0.25000 0.47600
80.807 0.30000 0.52000
82.833 0.35000 0.55000
84.433 0.40000 0.57700
85.713 0.45000 0.59800
86.233 0.50000 0.61900
86.686 0.55000 0.63400
87.006 0.60000 0.64700
87.313 0.65000 0.65900
87.579 0.70000 0.67000
87.566 0.75000 0.68000
87.219 0.80000 0.69400
86.326 0.85000 0.71600
84.340 0.90000 0.75400
80.167 0.95000 0.82400

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Kireev V.A.; Sitnikov I.P.: Bestimmung des Druckes und der Zusammensetzung des Dampfes und der Verdampfungswärme von Methanol-Chloroform-Mischungen und freie Energie und Entropie bei der ihre Bildungen. Zh.Fiz.Khim. 15 (1941) 492-499


Vapor-Liquid Equilibrium Data Set 424

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]
336.15 0.04000 0.10200
335.15 0.06500 0.15400
334.05 0.09500 0.21500
332.45 0.14600 0.30400
330.95 0.19600 0.37800
330.15 0.23000 0.42000
329.05 0.28700 0.47200
328.45 0.33200 0.50700
327.85 0.38300 0.54000
327.45 0.42500 0.56400
327.15 0.45900 0.58000
326.95 0.52000 0.60700
326.85 0.55700 0.61900
326.65 0.62800 0.64300
326.65 0.63600 0.64600
326.65 0.66700 0.65500
326.85 0.75300 0.68400
327.05 0.79700 0.70100
327.55 0.85500 0.73000
328.35 0.90400 0.76800
329.45 0.93700 0.81200
331.05 0.97000 0.87500

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Nagata I.: Isobaric Vapor-Liquid Equilibria for the Ternary System Chloroform-Methanol-Ethyl Acetate. J.Chem.Eng.Data 7 (1962) 367-373

Diagrams

Vapor-Liquid Equilibrium of Chloroform+Methanol
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Vapor-Liquid Equilibrium of Chloroform+Methanol
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Vapor-Liquid Equilibrium of Chloroform+Methanol
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Vapor-Liquid Equilibrium of Chloroform+Methanol
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List of All References

Source
Kireev V.A.; Sitnikov I.P.: Bestimmung des Druckes und der Zusammensetzung des Dampfes und der Verdampfungswärme von Methanol-Chloroform-Mischungen und freie Energie und Entropie bei der ihre Bildungen. Zh.Fiz.Khim. 15 (1941) 492-499
Nagata I.: Isobaric Vapor-Liquid Equilibria for the Ternary System Chloroform-Methanol-Ethyl Acetate. J.Chem.Eng.Data 7 (1962) 367-373

Vapor-Liquid Equilibrium Data Overview


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